MARC details
| 000 -LEADER |
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| fixed length control field |
07881cam a2200385 i 4500 |
| 001 - CONTROL NUMBER |
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| control field |
17693410 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
OSt |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20190508115239.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
130411s2013 njua b 001 0 eng |
| 010 ## - LIBRARY OF CONGRESS CONTROL NUMBER |
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| LC control number |
2013002855 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
9781118065648 (hardback) |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
DLC |
| Language of cataloging |
eng |
| Transcribing agency |
DLC |
| Description conventions |
rda |
| Modifying agency |
DLC |
| 042 ## - AUTHENTICATION CODE |
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| Authentication code |
pcc |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
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| Classification number |
QD502.5 |
| Item number |
.S86 2013 |
| 082 00 - DEWEY DECIMAL CLASSIFICATION NUMBER |
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| Classification number |
547.139 |
| Edition number |
23 |
| Item number |
S.X.O |
| 084 ## - OTHER CLASSIFICATION NUMBER |
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| Classification number |
SCI013040 |
| Source of number |
bisacsh |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
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| Personal name |
Sun, Xiaoping, |
| Dates associated with a name |
1960- |
| Relator term |
author. |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Organic mechanisms : |
| Remainder of title |
reactions, methodology, and biological applications / |
| Statement of responsibility, etc |
Xiaoping Sun, University of Charleston, Charleston, West Virginia, USA. |
| 264 #1 - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) |
|---|
| Place of publication, distribution, etc |
Hoboken, New Jersey : |
| Name of publisher, distributor, etc |
Wiley, |
| Date of publication, distribution, etc |
[2013] |
| 300 ## - PHYSICAL DESCRIPTION |
|---|
| Extent |
xiv, 418 pages : |
| Other physical details |
illustrations ; |
| Dimensions |
25 cm |
| 336 ## - CONTENT TYPE |
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| Content type term |
text |
| Source |
rdacontent |
| 337 ## - MEDIA TYPE |
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| Media type term |
unmediated |
| Source |
rdamedia |
| 338 ## - CARRIER TYPE |
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| Carrier type term |
volume |
| Source |
rdacarrier |
| 500 ## - GENERAL NOTE |
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| General note |
pharmacy bookfair2015 |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
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| Bibliography, etc |
Includes bibliographical references and index. |
| 505 8# - FORMATTED CONTENTS NOTE |
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| Formatted contents note |
Machine generated contents note: Chapter 1 Fundamental Principles 1.1 Reaction mechanisms and their importance 1.2 Elementary (concerted) and stepwise reactions 1.3 Molecularity 1.4 Kinetics 1.5 Thermodynamics 1.6 The transition state 1.7 The molecular orbital theory 1.8 Electrophiles/nucleophiles versus acids/bases 1.9 Isotope labeling References Problems Chapter 2 The Aliphatic C-H Bond Functionalization 2.1 Alkyl radicals: Bonding and their relative stability 2.2 Radical halogenations of the C-H bonds on sp3-hybridized carbons: Mechanism and nature of the transition states 2.3 Energetics of the radical halogenations of alkanes and their regioselectivity 2.4 Kinetics of radical halogenations of alkanes 2.5 Radical initiators 2.6 Transition-metal-compounds catalyzed alkane C-H bond activation and functionalization 2.7 Superacids catalyzed alkane C-H bond activation and functionalization 2.8 Nitration of aliphatic C-H bonds via the nitronium NO2+ ion 2.9 Enzyme catalyzed alkane C-H bond activation and functionalization: Biochemical methods References Problems Chapter 3 Functionalization of the Alkene C=C Bond by Electrophilic Additions 3.1 Markovnikov additions via intermediate carbocations 3.2 Electrophilic addition of hydrogen halides to conjugated dienes 3.3 Non-Markovnikov radical addition 3.4 Hydroboration: Concerted, Non-Markovnikov syn-addition 3.5 Transition-metal catalyzed hydrogenation of the alkene C=C bond (syn-addition) 3.6 Halogenation of the alkene C=C bond (Anti-addition): Mechanism and its stereochemistry References Problems Chapter 4 Functionalization of the Alkene C=C Bond by Cycloaddition Reactions 4.1 Cycloadditions of the alkene C=C bond to form three-membered rings 4.2 Cycloadditions to form four-membered rings 4.3 Deals-Alder cycloadditions of the alkene C=C bond to form six-membered rings 4.4 1,3-Dipolar cycloadditions of the C=C and other multiple bonds to form five-membered rings 4.5 Pericyclic reactions References Problems Chapter 5 The Aromatic C-H bond Functionalization and Related Reactions 5.1 Aromatic nitration: All reaction intermediates and full mechanism for the aromatic C-H bond substitution by nitronium (NO2+) and related electrophiles 5.2 Mechanisms and synthetic utility for aromatic C-H bond substitutions by other related electrophiles 5.3 The electrophilic aromatic C-H bond substitution reactions via SN1 and SN2 mechanisms 5.4 Substituent effects on the electrophilic aromatic substitution reactions 5.5 Isomerizations effected by the electrophilic aromatic substitution reactions 5.6 Electrophilic substitution reactions on the aromatic carbon-metal bonds: Mechanisms and synthetic applications 5.7 Nucleophilic aromatic substitution via a benzyne (aryne) intermediate: Functional group transformations on aromatic rings 5.8 Nucleophilic aromatic substitution via an anionic Meisenheimer complex 5.9 Biological applications of functionalized aromatic compounds References Problems Chapter 6 Nucleophilic Substitutions on sp3-Hybridized Carbons: Functional Group Transformations 6.1 Nucleophilic substitution on mono-functionalized sp3-hybridized carbon 6.2 Functional groups which are good and poor leaving groups 6.3 Good and poor nucleophiles 6.4 SN2 reactions: Kinetics, mechanism, and stereochemistry 6.5 Analysis of the SN2 mechanism using symmetry rules and molecular orbital theory 6.6 SN1 reactions: Kinetics, mechanism, and product development 6.7 Competitions between SN1 and SN2 reactions 6.8 Some useful SN1 and SN2 reactions: Mechanisms and synthetic perspectives 6.9 Biological applications of nucleophilic substitution reactions References Problems Chapter 7 Eliminations 7.1 E2 Elimination: Bimolecular b-elimination of H/LG and its regiochemistry and stereochemistry 7.2 Analysis of the E2 mechanism using symmetry rules and molecular orbital theory 7.3 Basicity versus nucleophilicity for various anions 7.4 Competition of E2 and SN2 reactions 7.5 E1 Elimination: Stepwise b-elimination of H/LG via an intermediate carbocation and its rate-law 7.6 Special b-elimination reactions 7.7 Elimination of LG1/LG2 in the compounds that contain two functional groups 7.8 a-Elimination giving a carbene: A mechanistic analysis using symmetry rules and molecular orbital theory 7.9 E1cb elimination and its biological applications References Problems Chapter 8 Nucleophilic Additions and Substitutions on Carbonyl Groups 8.1 Nucleophilic additions and substitutions of carbonyl compounds 8.2 Nucleophilic additions of aldehydes and ketones and their biological applications 8.3 Biological hydride donors NAD(P)H and FADH2 8.4 Activation of carboxylic acids via nucleophilic substitutions on the carbonyl carbons 8.5 Nucleophilic substitutions of acyl derivatives and their biological applications 8.6 Reduction of acyl derivatives by hydride donors 8.7 Kinetics of the Nucleophilic addition and substitution of acyl derivatives References Problems Chapter 9 Reactivity of the a-Hydrogen to Carbonyl Groups 9.1 Formation of enolates and their nucleophilicity 9.2 Alkylation of carbonyl compounds (aldehydes, ketones, and esters) via enolates and hydrazones 9.3 Aldol reactions 9.4 Acylation reactions of esters via enolates: Mechanism and synthetic utility 9.5 Roles of enolates in metabolic processes in living organisms References Problems Chapter 10 Rearrangements 10.1 Major types of rearrangements 10.2 Rearrangement of carbocations: 1,2-Shift 10.3 Neighboring leaving group facilitated 1,2-rearrangement 10.4 Carbene rearrangement: 1,2-Rearrangement of hydrogen facilitated by a lone pair of electrons 10.5 Claisen rearrangement 10.6 Photochemical isomerization of alkenes and its biological applications 10.7 Rearrangement of carbon-nitrogen-sulfur containing heterocycles References Problems . |
| 520 ## - SUMMARY, ETC. |
|---|
| Summary, etc |
"Emphasizing mechanistic aspects of organic reactions, Organic Mechanisms provides a useful guide for how to analyze, understand, approach, and solve the problems of organic reactions with the help of mechanistic studies. The author ties reaction mechanisms, synthetic methodology, and biochemical applications together and helps organic chemists improve the practice of synthetic reactions. With end-of-chapter problems and separate solutions manual, the book serves as a student-friendly textbook in advanced organic chemistry as well as a resource for practicing chemists"-- |
| Assigning source |
Provided by publisher. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name as entry element |
Organic reaction mechanisms. |
| 9 (RLIN) |
7512 |
| 650 #7 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name as entry element |
SCIENCE / Chemistry / Organic. |
| Source of heading or term |
bisacsh |
| 776 08 - ADDITIONAL PHYSICAL FORM ENTRY |
|---|
| Display text |
Online version: |
| Main entry heading |
Sun, Xiaoping, 1960- |
| Title |
Organic mechanisms |
| Place, publisher, and date of publication |
Hoboken, New Jersey : Wiley, [2013] |
| International Standard Book Number |
9781118507971 |
| Record control number |
(DLC) 2013015020 |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
|---|
| Materials specified |
Abstract |
| Uniform Resource Identifier |
<a href="http://repository.fue.edu.eg/xmlui/handle/123456789/2835">http://repository.fue.edu.eg/xmlui/handle/123456789/2835</a> |
| 906 ## - LOCAL DATA ELEMENT F, LDF (RLIN) |
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7 |
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| c |
orignew |
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| e |
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| f |
20 |
| g |
y-gencatlg |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Dewey Decimal Classification |
| Koha item type |
Books |