Pharmaceutical Organic Chemistry / S K Bhasin, Reena Gupta, Rajshree Khare.

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Front Cover -- Front Matter -- Copyright -- PREFACE-- Dedication -- Contents-- Chapter 1 -- Structure and Properties -- Introduction -- Wave Mechanical Model of Atom (Atomic Orbitals)-- Physical significance of Wave Function -- Quantum Numbers-- Principal quantum number (n)-- Magnetic quantum number (m) -- Shapes of Orbitals -- Shapes of s Orbitals-- Difference between 1s and 2s Orbitals -- Shapes of p Orbitals-- Shapes of d Orbitals-- Signs of Wave Functions -- s Orbitals-- p Orbitals-- d Orbitals-- Rules for Filling of Orbitals or Electronic Configuration of Atoms -- Aufbau Principle -- n+l rule or Bohr Bury's rule. Pauli's Exclusion Principle Applications -- Hund's Rule of Maximum Multiplicity -- Explanation -- Extra Stability of Half-Filled and Completely Filled Subshells -- Part -- BFormation of Molecules -- Introduction -- Valence Bond (VB) Theory -- Application of VB Theory: Formation of Hydrogen Molecule -- Limitations of Valence Bond Theory -- Molecular Orbital (MO) Theory -- Molecular Orbitals -- Conditions of Formation of Molecular Orbitals -- Differences Between Atomic and Molecular Orbitals-- Formation oF Bonding and Antibonding Molecular orbitals (LCAO Method). Bonding and Antibonding Molecular Orbitals in Terms of Wave Functions Differences between Bonding and Antibonding Molecular Orbitals -- Combination of Atomic Orbitals-Sigma (<U+0076>) and PI (<U+0073>) Molecular Orbitals -- Difference between <U+0076> and <U+0073> Molecular Orbitals -- comparison of Valence Bond Theory and Molecular Orbital Theory -- Hybridization -- Conditions for Hybridization -- Characteristics of Hybridization -- Types of Hybridization -- Intermolecular Forces-- Hydrogen Bonding -- Factors Responsible for the Formation of Hydrogen Bond and Strength of Hydrogen Bond -- Consequences of Hydrogen Bonding. Types of Hydrogen BondsHydrogen Bonding in Ice in Water-- Density of Water is Maximum at 4C -- Importance of Hydrogen Bonding-- Bond Dissociation Energies- - PART -- CAcids and Bases -- INTRODUCTION-- ARRHENIUS CONCEPT OF ACIDS AND BASES -- BRONSTED-LOWRY CONCEPT OF ACIDS AND BASES -- LEWIS CONCEPT OF ACIDS AND BASES-- Dissociation Constants of Acids and Their Strength-- Conjugate Acid-Base Pairs-- Relative Strength of Acids and Bases-- Advantages of Bronsted-Lowry Concept Over Arrhenius Concept-- Limitations of Bronsted-Lowry Concept-- Limitations of Lewis Concept. Effect of Substituents on the Strength of Lewis Acids and BasesInductive effect of the substituents-- Resonance effect of the substituents-- Steric effects of the substituents-- Chapter 2 --Nomenclature of Organic Compounds -- Introduction-- Iupac Nomenclature of Organic Compounds-- General Rules of IUPAC System-- Nomenclature of Hydrocarbons-- Nomenclature of Saturated Branched Chain Acyclic Hydrocarbon-- Nomenclature of Unsaturated Hydrocarbons-- Nomenclature of Cyclic (Alicyclic) Hydrocarbons-- Nomenclature of Polycyclic Hydrocarbons.